Spectroscopic Study of the E/Z Photoisomerization of a New Cyrhetrenyl Acylhydrazone: A Potential Photoswitch and Photosensitizer^†

Keyphrases

• Spectroscopic Studies 100%
• Z-E Isomerization 100%
• Photoswitches 100%
• Acylhydrazone 100%
• Photosensitizer 100%
• Photophysical Properties 66%
• First-order 33%
• 1H nuclear Magnetic Resonance (1H NMR) 33%
• Two-band 33%
• Irradiation 33%
• Sensitizer 33%
• Ligand-to-metal Charge Transfer 33%
• Switch-off 33%
• E Configuration 33%
• Isomerization Mechanism 33%
• Time-dependent Density Functional Theory 33%
• Charge Transfer Transition 33%
• Photosensitizing 33%
• Covalently Bonded 33%
• Molecular Photoswitches 33%
• All-d-metal 33%
• Yield Value 33%
• Singlet Oxygen 33%
• TD-DFT Calculations 33%
• Absorption Spectra 33%
• Good Yield 33%
• T-type 33%
• Quantum Yield 33%
• Short Half-life 33%
• UV-VIS Spectroscopy 33%
• Photochemical Properties 33%
• Spectral Changes 33%

INIS

• yields 100%
• oxygen 100%
• configuration 50%
• values 50%
• metals 50%
• switches 50%
• charges 50%
• irradiation 50%
• hydrogen 1 50%
• half-life 50%
• nitrogen dioxide 50%
• nmr 50%
• ligands 50%
• sensitizers 50%
• absorption spectra 50%
• isomerization 50%
• isomers 50%
• photochemistry 50%
• crystal structure 50%

Chemistry

• Photoswitch 100%
• Density Functional Theory 100%
• Photoisomerization 100%
• Spectroscopy 100%
• 1H NMR Spectroscopy 50%
• Nitrogen Dioxide 50%
• Time-Dependent Density Functional Theory 50%
• Crystal Structure 50%
• Quantum Yield 50%
• Charge Transfer Transition 50%
• UV/VIS Spectroscopy 50%
• Isomerization 50%
• Absorption Spectrum 50%