Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo; Paola A. Benavides; Colin McMillen; Sourav Saha

doi:10.1039/d2ma00606e

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo
, Paola A. Benavides
, Colin McMillen
, Sourav Saha

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

3 Citas (Scopus)

Resumen

Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10⁻⁷ S m⁻¹) than the neutral pristine MOF.

Idioma original	Inglés
Páginas (desde-hasta)	6157-6160
Número de páginas	4
Publicación	Materials Advances
Volumen	3
N.º	15
DOI	https://doi.org/10.1039/d2ma00606e
Estado	Publicada - 7 jul 2022
Publicado de forma externa	Sí

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abstract = "Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.",

author = "Gordillo, \{Monica A.\} and Benavides, \{Paola A.\} and Colin McMillen and Sourav Saha",

note = "Publisher Copyright: {\textcopyright} 2022 The Author(s). ",

year = "2022",

month = jul,

day = "7",

doi = "10.1039/d2ma00606e",

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journal = "Materials Advances",

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Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand. / Gordillo, Monica A.; Benavides, Paola A.; McMillen, Colin et al.
En: Materials Advances, Vol. 3, N.º 15, 07.07.2022, p. 6157-6160.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

TY - JOUR

T1 - Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

AU - Gordillo, Monica A.

AU - Benavides, Paola A.

AU - McMillen, Colin

AU - Saha, Sourav

PY - 2022/7/7

Y1 - 2022/7/7

N2 - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

AB - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

UR - https://www.scopus.com/pages/publications/85134398387

U2 - 10.1039/d2ma00606e

DO - 10.1039/d2ma00606e

M3 - Article

AN - SCOPUS:85134398387

SN - 2633-5409

VL - 3

SP - 6157

EP - 6160

JO - Materials Advances

JF - Materials Advances

IS - 15

ER -

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

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