Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo; Paola A. Benavides; Colin McMillen; Sourav Saha

doi:10.1039/d2ma00606e

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo, Paola A. Benavides, Colin McMillen, Sourav Saha

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

3 Citas (Scopus)

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Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10⁻⁷ S m⁻¹) than the neutral pristine MOF.

Idioma original	Inglés
Páginas (desde-hasta)	6157-6160
Número de páginas	4
Publicación	Materials Advances
Volumen	3
N.º	15
DOI	https://doi.org/10.1039/d2ma00606e
Estado	Publicada - 7 jul. 2022
Publicado de forma externa	Sí

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abstract = "Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.",

author = "Gordillo, {Monica A.} and Benavides, {Paola A.} and Colin McMillen and Sourav Saha",

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Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand. / Gordillo, Monica A.; Benavides, Paola A.; McMillen, Colin et al.
En: Materials Advances, Vol. 3, N.º 15, 07.07.2022, p. 6157-6160.

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

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T1 - Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

AU - Gordillo, Monica A.

AU - Benavides, Paola A.

AU - McMillen, Colin

AU - Saha, Sourav

PY - 2022/7/7

Y1 - 2022/7/7

N2 - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

AB - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

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Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

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