TY - JOUR
T1 - Simple and low-cost synthesis of CuO nanosheets for visible-light-driven photocatalytic degradation of textile dyes
AU - Rao, Martha Purnachander
AU - Sathishkumar, Pannerselvam
AU - Mangalaraja, Ramalinga Viswanathan
AU - Asiri, Abdullah M.
AU - Sivashanmugam, Palani
AU - Anandan, Sambandam
N1 - Publisher Copyright:
© 2018 Elsevier Ltd. All rights reserved.
PY - 2018/4
Y1 - 2018/4
N2 - In this study, an attempt was made to synthesize highly pure CuO nanosheets by a simple and economically viable solution phase method; and well characterized by FTIR, XRD, SEM and EDS analyses. The SEM morphological analysis demonstrates the existence of sheet-like architecture with the length and width of 250-350nm and 200±20nm while XRD illustrates the presence of pure monoclinic phase. A suitable growth mechanism for CuO nanosheets formation explained clearly. The calculated band gap from diffuse reflectance UV-vis analysis is 1.31eV. Moreover, the photocatalytic studies revealed that the nanosheets were shown superior degradation efficiency in visible light irradiation. From the observed results, it is found that the Methylene Blue (MB) has enhanced adsorption compared to Rhodamine - B (RhB) at the nanocatalysts surface can effectively react with the hydroxyl radicals generated in its vicinity to attain the maximum degradation.
AB - In this study, an attempt was made to synthesize highly pure CuO nanosheets by a simple and economically viable solution phase method; and well characterized by FTIR, XRD, SEM and EDS analyses. The SEM morphological analysis demonstrates the existence of sheet-like architecture with the length and width of 250-350nm and 200±20nm while XRD illustrates the presence of pure monoclinic phase. A suitable growth mechanism for CuO nanosheets formation explained clearly. The calculated band gap from diffuse reflectance UV-vis analysis is 1.31eV. Moreover, the photocatalytic studies revealed that the nanosheets were shown superior degradation efficiency in visible light irradiation. From the observed results, it is found that the Methylene Blue (MB) has enhanced adsorption compared to Rhodamine - B (RhB) at the nanocatalysts surface can effectively react with the hydroxyl radicals generated in its vicinity to attain the maximum degradation.
KW - CuO nanocatalysts
KW - Dye degradation
KW - Nanosheet
KW - Solution-phase method
KW - Visible light
UR - http://www.scopus.com/inward/record.url?scp=85043606579&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2018.03.008
DO - 10.1016/j.jece.2018.03.008
M3 - Article
AN - SCOPUS:85043606579
SN - 2213-3437
VL - 6
SP - 2003
EP - 2010
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 2
ER -