NiFe Layered Double Hydroxide Electrocatalyst Prepared via an Electrochemical Deposition Method for the Oxygen Evolution Reaction

Murugesan Praveen Kumar; Moorthy Sasikumar; Arunachalam Arulraj; Venugopalan Rajasudha; Govindhasamy Murugadoss; Manavalan Rajesh Kumar; Shaik Gouse Peera; Ramalinga Viswanathan Mangalaraja

doi:10.3390/catal12111470

NiFe Layered Double Hydroxide Electrocatalyst Prepared via an Electrochemical Deposition Method for the Oxygen Evolution Reaction

Murugesan Praveen Kumar, Moorthy Sasikumar, Arunachalam Arulraj, Venugopalan Rajasudha, Govindhasamy Murugadoss, Manavalan Rajesh Kumar, Shaik Gouse Peera, Ramalinga Viswanathan Mangalaraja

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Herein, we aimed to obtain NiFe layered double hydroxide (LDH) with a controlled phase and surface morphology as a highly active and stable oxygen evolution catalyst via the electrochemical deposition method, which was thermodynamically stable for the oxygen evolution reaction (OER) in an alkaline medium. The NiFe-LDH sample was analyzed by sophisticated instruments and tested as an electrocatalyst on Toray carbon (TC). The NiFe-LDH electrocatalyst showed an excellent performance with lower overpotential of 0.27 V at 35 mA cm⁻² and higher density of 125 mA cm⁻² for OER in the 1 M KOH electrolyte solution. Moreover, the prepared catalyst exhibited unpredictable long-time stability for 700 h. From our knowledge, NiFe-LDH is a robust highly stable electrocatalyst compared to the recent reports.

Original language	English
Article number	1470
Journal	Catalysts
Volume	12
Issue number	11
DOIs	https://doi.org/10.3390/catal12111470
State	Published - Nov 2022
Externally published	Yes

Keywords

(Oxy)hydroxides phases
NiFe-LDH electrocatalyst
OER
electrochemical deposition
long-time stability

Access to Document

10.3390/catal12111470

Cite this

@article{c6ce4efaedce4c7ea8ecb42ec4cb4ee2,

title = "NiFe Layered Double Hydroxide Electrocatalyst Prepared via an Electrochemical Deposition Method for the Oxygen Evolution Reaction",

abstract = "Herein, we aimed to obtain NiFe layered double hydroxide (LDH) with a controlled phase and surface morphology as a highly active and stable oxygen evolution catalyst via the electrochemical deposition method, which was thermodynamically stable for the oxygen evolution reaction (OER) in an alkaline medium. The NiFe-LDH sample was analyzed by sophisticated instruments and tested as an electrocatalyst on Toray carbon (TC). The NiFe-LDH electrocatalyst showed an excellent performance with lower overpotential of 0.27 V at 35 mA cm−2 and higher density of 125 mA cm−2 for OER in the 1 M KOH electrolyte solution. Moreover, the prepared catalyst exhibited unpredictable long-time stability for 700 h. From our knowledge, NiFe-LDH is a robust highly stable electrocatalyst compared to the recent reports.",

keywords = "(Oxy)hydroxides phases, NiFe-LDH electrocatalyst, OER, electrochemical deposition, long-time stability",

author = "{Praveen Kumar}, Murugesan and Moorthy Sasikumar and Arunachalam Arulraj and Venugopalan Rajasudha and Govindhasamy Murugadoss and Kumar, {Manavalan Rajesh} and {Gouse Peera}, Shaik and Mangalaraja, {Ramalinga Viswanathan}",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",

year = "2022",

month = nov,

doi = "10.3390/catal12111470",

language = "English",

volume = "12",

journal = "Catalysts",

issn = "2073-4344",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "11",

}

TY - JOUR

T1 - NiFe Layered Double Hydroxide Electrocatalyst Prepared via an Electrochemical Deposition Method for the Oxygen Evolution Reaction

AU - Praveen Kumar, Murugesan

AU - Sasikumar, Moorthy

AU - Arulraj, Arunachalam

AU - Rajasudha, Venugopalan

AU - Murugadoss, Govindhasamy

AU - Kumar, Manavalan Rajesh

AU - Gouse Peera, Shaik

AU - Mangalaraja, Ramalinga Viswanathan

PY - 2022/11

Y1 - 2022/11

N2 - Herein, we aimed to obtain NiFe layered double hydroxide (LDH) with a controlled phase and surface morphology as a highly active and stable oxygen evolution catalyst via the electrochemical deposition method, which was thermodynamically stable for the oxygen evolution reaction (OER) in an alkaline medium. The NiFe-LDH sample was analyzed by sophisticated instruments and tested as an electrocatalyst on Toray carbon (TC). The NiFe-LDH electrocatalyst showed an excellent performance with lower overpotential of 0.27 V at 35 mA cm−2 and higher density of 125 mA cm−2 for OER in the 1 M KOH electrolyte solution. Moreover, the prepared catalyst exhibited unpredictable long-time stability for 700 h. From our knowledge, NiFe-LDH is a robust highly stable electrocatalyst compared to the recent reports.

AB - Herein, we aimed to obtain NiFe layered double hydroxide (LDH) with a controlled phase and surface morphology as a highly active and stable oxygen evolution catalyst via the electrochemical deposition method, which was thermodynamically stable for the oxygen evolution reaction (OER) in an alkaline medium. The NiFe-LDH sample was analyzed by sophisticated instruments and tested as an electrocatalyst on Toray carbon (TC). The NiFe-LDH electrocatalyst showed an excellent performance with lower overpotential of 0.27 V at 35 mA cm−2 and higher density of 125 mA cm−2 for OER in the 1 M KOH electrolyte solution. Moreover, the prepared catalyst exhibited unpredictable long-time stability for 700 h. From our knowledge, NiFe-LDH is a robust highly stable electrocatalyst compared to the recent reports.

KW - (Oxy)hydroxides phases

KW - NiFe-LDH electrocatalyst

KW - OER

KW - electrochemical deposition

KW - long-time stability

UR - http://www.scopus.com/inward/record.url?scp=85148749917&partnerID=8YFLogxK

U2 - 10.3390/catal12111470

DO - 10.3390/catal12111470

M3 - Article

AN - SCOPUS:85148749917

SN - 2073-4344

VL - 12

JO - Catalysts

JF - Catalysts

IS - 11

M1 - 1470

ER -

NiFe Layered Double Hydroxide Electrocatalyst Prepared via an Electrochemical Deposition Method for the Oxygen Evolution Reaction

Abstract

Keywords

Access to Document

Fingerprint

Cite this