Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo; Paola A. Benavides; Colin McMillen; Sourav Saha

doi:10.1039/d2ma00606e

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

Monica A. Gordillo, Paola A. Benavides, Colin McMillen, Sourav Saha

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10⁻⁷ S m⁻¹) than the neutral pristine MOF.

Original language	English
Pages (from-to)	6157-6160
Number of pages	4
Journal	Materials Advances
Volume	3
Issue number	15
DOIs	https://doi.org/10.1039/d2ma00606e
State	Published - 7 Jul 2022
Externally published	Yes

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abstract = "Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.",

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AU - Gordillo, Monica A.

AU - Benavides, Paola A.

AU - McMillen, Colin

AU - Saha, Sourav

PY - 2022/7/7

Y1 - 2022/7/7

N2 - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

AB - Novel columnar lanthanide metal-organic frameworks (Ln-MOFs) based on a butterfly-shaped electron-rich π-extended tetrathia-fulvalene ligand (ExTTFTB) were synthesized and their electronic properties were investigated. Upon iodine-induced ligand oxidation, the Tb-MOF displayed ca. 100-fold higher electrical conductivity (5 × 10−7 S m−1) than the neutral pristine MOF.

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DO - 10.1039/d2ma00606e

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EP - 6160

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JF - Materials Advances

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ER -

Iodine-induced electrical conductivity of novel columnar lanthanide metal-organic frameworks based on a butterfly-shaped π-extended tetrathiafulvalene ligand

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