Fetio3 perovskite nanoparticles for efficient electrochemical water splitting

Periyannan Kaleeswarran, Murugesan Praveen Kumar, Ramalinga Viswanathan Mangalaraja, Unalome Wetwatana Hartley, Moorthy Sasikumar, Rajasudha Venugopalan, Manavalan Rajesh Kumar, Jothi Ramalingam Rajabathar, Shaik Gouse Peera, Govindhasamy Murugadoss

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The use of water splitting has been investigated as a good alternate for storing electrical energy. While the general interest in developing non-toxic, high-performance, and economically feasible catalysts for oxygen evolution reaction (OER) is noteworthy, there is also significant interest in water splitting research. Recently, perovskite-type oxides have performed as an alternative to non-precious metal catalysts and can act as a new class of effective catalysts in water splitting systems. Herein, a perovskite-structured FeTiO3 was prepared via a facile one-step solvothermal method using ionic liquid as templates. The results of structural and morphological studies have supported the formation of FeTiO3 perovskite. Furthermore, FeTiO3 perovskite demonstrated OER activity with a lower onset potential of 1.45 V vs. RHE and Tafel slope value of 0.133 V.dec-1 at 1 M KOH solution using mercury/mercurous oxide (Hg/HgO) were used as working electrodes.

Original languageEnglish
Article number1028
JournalCatalysts
Volume11
Issue number9
DOIs
StatePublished - Sep 2021
Externally publishedYes

Keywords

  • FeTiO3
  • Hybrid electrocatalyst
  • Ionic liquids
  • OER
  • Solvothermal method
  • Water splitting
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